Umm, Non Merged set is the easiest since it's 1 file = 1 working game, Merged still requires bios and Split is where everything is broken out and is more cumbersome.
You said Not Merged so i'm not sure if you mean Non Merged or Split.
If you have the Non Merged set and use the old import method (not the Mame Full Set Import tool you can easily copy out a rom set using the Export/Copy ROM Files tool.